Nanocomposite Polymer Electrolytes of Sodium Alginate and Montmorillonite Clay

Nanocomposite polymer electrolytes (NPEs) were synthesized using sodium alginate (Alg) and either sodium (SCa-3-Na⁺)- or lithium (SCa-3-Li⁺)-modified montmorillonite clays. The samples were characterized by structural, optical, and electrical properties. SCa-3-Na⁺ and SCa-3-Li⁺ clays’ X-ray structural analyses revealed peaks at 2θ = 7.2° and 6.7° that corresponded to the interlamellar distances of 12.3 and 12.8 Å, respectively. Alg-based NPEs X-ray diffractograms showed exfoliated structures for samples with low clay percentages. The increase of clay content promoted the formation of intercalated structures. Electrochemical Impedance Spectroscopy revealed that Alg-based NPEs with 5 wt% of SCa-3-Na⁺ clay presented the highest conductivity of 1.96 × 10⁻² S/cm², and Alg with 10 wt% of SCa-3-Li⁺ showed conductivity of 1.30 × 10⁻² S/cm², both measured at 70 °C. From UV-Vis spectroscopy, it was possible to infer that increasing concentration of clay promoted a decrease of the samples’ transmittance and, consequently, an increase of their reflectance.     

Synthesis of attapulgite-MnO2 nanocomposite from manganese complex by ultrasound for hydrogen storage

The research included the synthesis of a new complex of manganese with 3,4,5-tri-methoxybenzoic acid in the presence of triethylamine as a base to which gives the complex with formula [Mn (TMB)₂].2H₂O. This complex was characterized by FTIR, CHN, magnetic susceptibility and thermal analysis. Furthermore, this complex was used as a novel precursor of manganese in preparing the attapulgite-MnO₂ nanocomposite by one-pot addition method using ultrasound. The resulting nanocomposite was characterized by X-ray diffraction and TEM and the results prove that this composite was found as nanochannel of the diameter 45 nm decorated with 26–41 nm of MnO₂ nanoparticles. The attapulgite-MnO₂ nanocomposite was used in the application of hydrogen storage, and the results proved that attapulgite-MnO₂ nanocomposite has the ability to store 3.55 wt% of hydrogen under a pressure of 90 bar and a temperature of 77 K. Furthermore, the measurement demonstrated that increasing the pressure increased the stored hydrogen, implying that the stored gas will be liberated by altering the pressure, implying that the storage will be of the physical kind.     

改性膨胀土路堤填筑含水量优化试验研究

在控制含水量的前提下,对分别掺入不同量石灰、不同量水泥改性膨胀土试件进行强度和膨胀量试验,得到不同含 水量及不同石灰(水泥)掺量对改性膨胀土强度和膨胀性的影响,通过对实验所得数据的分析,找出含水量和掺石灰(水泥)剂 量的最佳融合点,并据此对膨胀土路堤填料的改性施工提出了一些有益的建议。     

软粘土卸载特性计算模型研究

本文从三个方面对软粘土的卸载特性进行了理论研究。采用太沙基一维固结理论，编制了内嵌固结计算的修正剑桥模型程序．对软粘土卸载强度进行了分析。推导了基于修正剑桥模型的孔压表达式并编制了相应的程序对软粘土的卸载孔压特性进行了研究，结果显示，在伸长条件下．孔压先由零逐渐发展到负的最大值．然后又逐渐减小至零。突破零位后，发展成为正孔压并最后达到正的最大值。围压越大，产生的负孔压的极值越大，最终的正孔压越小。将传统边界面模型的线弹性卸载过程改进为弹塑性．建立了软粘土的边界面广义弹塑性模型，从而使边界面模型可用于分析软粘土卸载过程中的塑性变形问题。理论分析结果与试验进行了比较验证，证明理论研究方法是可行的。     

冲击荷载作用下粘土孔隙水压的数值分析

为了分析冲击荷载作用下粘土的孔隙水压力的增长规律，为分析粘土介质的动态响应、动力固结加固提供理论依据，将冲击瞬态荷载简化为三角形荷载，通过编制瞬变动态弹塑性有限元程序，对冲击荷载作用下粘土孔隙水压的动态响应进行了模拟，得出了冲击荷载作用下粘土孔隙水压的增长规律，发现孔隙水压力峰值无论是随水平距离还是随深度的增加均呈指数形式衰减，和实际工程施工中孔隙水压的监测数据相吻合。     

Non-linear Heat and Mass Transfer During Convective Drying of Kaolin Cylinder Under Non-steady Conditions

The self-consistent model of heat and mass transfer during convective drying of capillary porous media describing both the first and the second periods of drying is presented in Musielak (Wydawnictwo Politechniki Poznańskiej, seria Rozprawy, nr 386 (2004a); Chem. Process Eng. 25, 393–409 (2004b)). The results of simulations of processes in steady conditions are shown (Musielak Wydawnictwo Politechniki Poznańskiej, seria Rozprawy, nr 386 (2004a); Chem. Process Eng. 25, 393–409 (2004b)). The main aim of the present work is to compare experimental results with those from numerical simulations. Three convective drying processes have been performed experimentally. The first and the second periods of drying are considered, during which the humidity of air in the dryer changes due to evaporation. The first process is used to establish drying parameters, whereafter the two remaining processes are simulated. Good agreement between experimental and simulation results is found, both qualitative and quantitative.     

大埋深粘土三轴高压卸载变形与强度特征

以取自山东巨野矿区埋深近 4 30～ 6 0 0m的深部粘土样为例 ,分析测试了土的常规物理力学性质参数。考虑该埋深土的天然应力水平及其在煤矿建井开挖中的卸载应力变化 ,在三轴伺服仪上 ,进行三向等压分别达 11MPa、12MPa、14MPa下的卸除围压、保持轴压的三轴高压卸载试验 ,分析了深部粘土三轴高压卸载变形和强度特点 ,得到了相关力学参数。成果丰富了土的高压卸载力学性研究 ,并为巨野矿区煤矿立井建设提供了工程地质基础参数     

红粘土的微结构及其概化模型

本文论述红粘土的物质组成和微结构特征,在此基础上提出了红粘土微结构的概化模型,并根据这种模型对红粘土的工程特性进行了探讨。     

沿海软粘土取土质量的对比分析

本文在简要介绍固定活塞式薄壁取土器取土技术基础上，详尽分析了在连云港、赤湾港和广深路所进行的软粘土取土技术对比试验结果。试验结果表明，土样扰动对于室内所测定的力学性指标影响极大，但对物理性指标影响不大。研究结果还有力地证明，只要操作正确，采用薄壁取土器能取得高质量土样，而采用敞口式厚壁取土器取出的土样扰动较大。     

苏州阳澄湖地区淤泥质粘土工程地质特性探讨

苏州阳澄湖周围的沼积湖积平原存在一种性质较为特殊的淤泥质粘土,其亲水性粘土矿物含量和液塑限指标均较高,但在天然状态下虽具一定的胀缩性却未达到膨胀土的标准,可是经过扰动压实后,随着干密度的增大和含水量的减少却表现出较强的胀缩性,即转变为“人工膨胀土”[1]。本文通过苏州阳澄湖东北方向某一级公路附近3个取土场土样的试验分析,探讨了此地区这种淤泥质粘土的特殊性,为以后的工程施工提供了科学依据。